2017年9月
Lithium diffusion in spinel Li4Ti5O12 and LiTi2O4 films detected with Li-8 beta-NMR
PHYSICAL REVIEW B
- 巻
- 96
- 号
- 9
- 開始ページ
- 094402
- 終了ページ
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1103/PhysRevB.96.094402
- 出版者・発行元
- AMER PHYSICAL SOC
Diffusion of Li+ in (111) oriented thin films of the spinels Li4Ti5O12 and LiTi2O4 has been studied with Li-8 beta-detected NMR in the temperature range between 5 and 310 K. In Li4Ti5O12, the spin-lattice relaxation rate (1/T-1) versus temperature shows a clear maximum around 100 K (=T-max) which we attribute to magnetic freezing of dilute Ti3+ local magnetic moments, consistent with the results of magnetization and muon spin relaxation (mu(+) SR) measurements. The decrease in 1/T-1 with temperature above T-max indicates that Li+ starts to diffuse with a thermal activation energy (E-a) of 0.11(1) eV. In LiTi2O4, on the contrary, as temperature increases from 200 K, 1/T-1 increases monotonically up to 310 K. This suggests that Li also starts to diffuse above 200 K with Ea = 0.16(2) eV in LiTi2O4. Comparison with conventional Li-NMR on Li4Ti5O12 implies that both beta-NMR and mu(+) SR sense short-range Li motion, i.e., a jump diffusion of Li+ to the nearest neighboring sites.
- リンク情報
- ID情報
-
- DOI : 10.1103/PhysRevB.96.094402
- ISSN : 2469-9950
- eISSN : 2469-9969
- Web of Science ID : WOS:000408822900004