論文

査読有り
2017年9月

Lithium diffusion in spinel Li4Ti5O12 and LiTi2O4 films detected with Li-8 beta-NMR

PHYSICAL REVIEW B
  • Jun Sugiyama
  • Izumi Umegaki
  • Takeshi Uyama
  • Ryan M. L. McFadden
  • Susumu Shiraki
  • Taro Hitosugi
  • Zaher Salman
  • Hassan Saadaoui
  • Gerald D. Morris
  • W. Andrew MacFarlane
  • Robert F. Kiefl
  • 全て表示

96
9
開始ページ
094402
終了ページ
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1103/PhysRevB.96.094402
出版者・発行元
AMER PHYSICAL SOC

Diffusion of Li+ in (111) oriented thin films of the spinels Li4Ti5O12 and LiTi2O4 has been studied with Li-8 beta-detected NMR in the temperature range between 5 and 310 K. In Li4Ti5O12, the spin-lattice relaxation rate (1/T-1) versus temperature shows a clear maximum around 100 K (=T-max) which we attribute to magnetic freezing of dilute Ti3+ local magnetic moments, consistent with the results of magnetization and muon spin relaxation (mu(+) SR) measurements. The decrease in 1/T-1 with temperature above T-max indicates that Li+ starts to diffuse with a thermal activation energy (E-a) of 0.11(1) eV. In LiTi2O4, on the contrary, as temperature increases from 200 K, 1/T-1 increases monotonically up to 310 K. This suggests that Li also starts to diffuse above 200 K with Ea = 0.16(2) eV in LiTi2O4. Comparison with conventional Li-NMR on Li4Ti5O12 implies that both beta-NMR and mu(+) SR sense short-range Li motion, i.e., a jump diffusion of Li+ to the nearest neighboring sites.

リンク情報
DOI
https://doi.org/10.1103/PhysRevB.96.094402
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000408822900004&DestApp=WOS_CPL
ID情報
  • DOI : 10.1103/PhysRevB.96.094402
  • ISSN : 2469-9950
  • eISSN : 2469-9969
  • Web of Science ID : WOS:000408822900004

エクスポート
BibTeX RIS