Papers

Peer-reviewed
2017

Competition between the micellization and the liquid-liquid phase separation in amphiphilic block copolymer solutions

Polymer Journal
  • Sato, T.
  • ,
  • Takahashi, R.

Volume
49
Number
2
First page
273
Last page
277
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1038/pj.2016.110
Publisher
NATURE PUBLISHING GROUP

We have formulated the mixing Gibbs energy density for the micelle phase of an amphiphilic block copolymer solution using mean-field lattice theory. We have found a transition between the micellization and the liquid-liquid phase separation in this solution by comparing the mixing Gibbs energy density for the micelle phase with that for the homogeneous phase. Micellization is preferred over the liquid-liquid phase separation not only at a higher amphiphilicity of the block copolymer chain but also at a higher degree of polymerization of the copolymer.

Link information
DOI
https://doi.org/10.1038/pj.2016.110
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000394268000007&DestApp=WOS_CPL
Scopus Url
http://www.scopus.com/inward/record.url?eid=2-s2.0-85011672624&partnerID=MN8TOARS
URL
http://orcid.org/0000-0003-2168-9436
ID information
  • DOI : 10.1038/pj.2016.110
  • ISSN : 0032-3896
  • eISSN : 1349-0540
  • ORCID - Put Code : 30440161
  • SCOPUS ID : 85011672624
  • Web of Science ID : WOS:000394268000007

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