2017
Competition between the micellization and the liquid-liquid phase separation in amphiphilic block copolymer solutions
Polymer Journal
- ,
- Volume
- 49
- Number
- 2
- First page
- 273
- Last page
- 277
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1038/pj.2016.110
- Publisher
- NATURE PUBLISHING GROUP
We have formulated the mixing Gibbs energy density for the micelle phase of an amphiphilic block copolymer solution using mean-field lattice theory. We have found a transition between the micellization and the liquid-liquid phase separation in this solution by comparing the mixing Gibbs energy density for the micelle phase with that for the homogeneous phase. Micellization is preferred over the liquid-liquid phase separation not only at a higher amphiphilicity of the block copolymer chain but also at a higher degree of polymerization of the copolymer.
- Link information
-
- DOI
- https://doi.org/10.1038/pj.2016.110
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000394268000007&DestApp=WOS_CPL
- Scopus Url
- http://www.scopus.com/inward/record.url?eid=2-s2.0-85011672624&partnerID=MN8TOARS
- URL
- http://orcid.org/0000-0003-2168-9436
- ID information
-
- DOI : 10.1038/pj.2016.110
- ISSN : 0032-3896
- eISSN : 1349-0540
- ORCID - Put Code : 30440161
- SCOPUS ID : 85011672624
- Web of Science ID : WOS:000394268000007