2021年4月1日
Development of spin-contrast-variation neutron powder diffractometry for extracting the structure factor of hydrogen atoms
Journal of Applied Crystallography
- 巻
- 54
- 号
- 2
- 開始ページ
- 454
- 終了ページ
- 460
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1107/s1600576721000303
- 出版者・発行元
- International Union of Crystallography (IUCr)
A spin-contrast-variation neutron powder diffractometry technique that extracts the structure factor of hydrogen atoms, <italic>i.e.</italic> the contribution of hydrogen atoms to a crystal's structure factor, has been developed. Crystals of L-glutamic acid were dispersed in a D-polystyrene matrix containing 4-methacryloyloxy-2,2,6,6,-tetramethyl-1-piperidinyloxy to polarize their proton spins dynamically. The intensities of the diffraction peaks of the sample changed according to the proton polarization, and the structure factor of the hydrogen atoms was extracted from the proton-polarization-dependent intensities. This technique is expected to enable analyses of the structures of hydrogen-containing materials that are difficult to determine with conventional powder diffractometry.
- リンク情報
- ID情報
-
- DOI : 10.1107/s1600576721000303
- eISSN : 1600-5767