論文

査読有り
2014年9月

Paramagnetic shimming for wide-range variable-field NMR

JOURNAL OF MAGNETIC RESONANCE
  • Naoki Ichijo
  • ,
  • Kazuyuki Takeda
  • ,
  • K. Takegoshi

246
開始ページ
57
終了ページ
61
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.jmr.2014.06.022
出版者・発行元
ACADEMIC PRESS INC ELSEVIER SCIENCE

We propose a new passive shimming strategy for variable-field NMR experiments, in which the magnetic field produced by paramagnetic shim pieces placed inside the magnet bore compensates the inhomogeneity of a variable-field magnet for a wide range of magnet currents. Paramagnetic shimming is demonstrated in Li-7, Rb-87, and Sc-45 NMR of a liquid solution sample in magnetic fields of 3.4, 4.0, and 5.4 T at a fixed carrier frequency of 56.0 MHz. Since both the main-field inhomogeneity and the paramagnetic magnetization are proportional to the main-magnet current, the resonance lines are equally narrowed by the improved field homogeneity with an identical configuration of the paramagnetic shim pieces. Paramagnetic shimming presented in this work opens the possibility of high-resolution variable-field NMR experiments. (C) 2014 Elsevier Inc. All rights reserved.

リンク情報
DOI
https://doi.org/10.1016/j.jmr.2014.06.022
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000342120500009&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.jmr.2014.06.022
  • ISSN : 1090-7807
  • eISSN : 1096-0856
  • Web of Science ID : WOS:000342120500009

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