2022年2月28日
Electrochemical control and protonation of the strontium iron oxide SrFeOy by using proton-conducting electrolyte
Applied Physics Letters
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- 巻
- 120
- 号
- 9
- 開始ページ
- 091601
- 終了ページ
- 091601
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1063/5.0083209
- 出版者・発行元
- {AIP} Publishing
To electrochemically control structural and transport properties of oxygen-deficient perovskite SrFeO y (2.5 ≦ y ≦ 3) (SFO) epitaxial films, we employed electric-field-effect transistor structures in which the proton-conducting solid electrolyte Nafion is used as a gate insulator. When a positive gate voltage ( VGS) is applied and protons are injected toward the film channel layer, the SFO films are electrochemically reduced, leading to increases in the channel resistance. On the other hand, when a negative VGS is applied and protons are removed, the SFO films are oxidized, and as a result, the channel resistances decrease. In addition, we found that the electrochemically reduced SFO films accommodate protons, forming the proton-containing oxide H xSrFeO2.5 whose proton concentration is determined by elastic recoil detection analysis to be x ∼ 0.11. Our results indicate the usefulness of the proton-conducting solid electrolyte for electrochemically controlling transition metal oxides and for exploring proton-containing oxides.
- リンク情報
- ID情報
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- DOI : 10.1063/5.0083209
- ISSN : 0003-6951
- eISSN : 1077-3118
- ORCIDのPut Code : 109079780