2010
Bio-supramolecular photochirogenesis with molecular chaperone: enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate mediated by prefoldin
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
- Volume
- 9
- Number
- 5
- First page
- 655
- Last page
- 660
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1039/b9pp00186g
- Publisher
- ROYAL SOC CHEMISTRY
Photocyclodimerization of 2-anthracenecarboxylate mediated by molecular chaperone protein was performed for the first time to afford chiral syn-head-to-tail and anti-head-to-head dimers (2 and 3) in 10% and 16% enantiomeric excess, respectively, with enhanced yields of sterically and electrostatically less-favored head-to-head dimers (3 and 4).
- Link information
- ID information
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- DOI : 10.1039/b9pp00186g
- ISSN : 1474-905X
- Web of Science ID : WOS:000277318300005