2013年3月
Synthesis and Optical Properties of Stable Gallafluorene Derivatives: Investigation of Their Emission via Triplet States
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- ,
- ,
- 巻
- 135
- 号
- 11
- 開始ページ
- 4211
- 終了ページ
- 4214
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ja400287y
- 出版者・発行元
- AMER CHEMICAL SOC
We designed and synthesized air- and moisture-stable gallafluorenes in which two benzene rings were bridged by the four-coordinate gallium atoms. The series of gallafluorenes were prepared by introducing electron-donating and -withdrawing groups through Suzuki-Miyaura coupling reactions. The gallafluorenes showed unique emissions via their triplet states in the presence of B(C6F5)(3). These emissions were obtained via the triplet exciplex of gallafluorene and B(C6F5)(3).
- リンク情報
- ID情報
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- DOI : 10.1021/ja400287y
- ISSN : 0002-7863
- Web of Science ID : WOS:000316774100013