2015年9月
Synthesis of pi-Conjugated Polymers Containing Dibenzosilepin Moieties with Pentacoordinate Silicon
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
- ,
- ,
- 巻
- 88
- 号
- 9
- 開始ページ
- 1350
- 終了ページ
- 1355
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/bcsj.20150162
- 出版者・発行元
- CHEMICAL SOC JAPAN
Benzo[h]quinolyldibenzo[b,f]silepin containing pentacoordinate silicon was incorporated into pi-conjugated polymers. Substituent effects were investigated from UV-vis absorption and photoluminescence spectra. The extension of pi-conjugation involving pentacoordinate silicon was suggested from the characteristic absorption and emission bands through the polymer chain at meta-positions toward silicon in the silepin rings. The polymers containing the fluorinated silicon showed bathochromic shift compared to that from the methylated silicon-containing polymers. Polymerization at para-positions toward silicon resulted in the formation of short conjugation length. Finally, the emission band from the charge-transfer transition was observed in photoluminescence spectra of the fluorinated polymer.
- リンク情報
- ID情報
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- DOI : 10.1246/bcsj.20150162
- ISSN : 0009-2673
- eISSN : 1348-0634
- Web of Science ID : WOS:000361343600020