2015年3月
Synthesis of Air- and Moisture-Stable Dibenzogallepins: Control of Planarity of Seven-Membered Rings in Solid States by Coordination to Gallium Atoms
ORGANIC LETTERS
- ,
- ,
- ,
- 巻
- 17
- 号
- 6
- 開始ページ
- 1593
- 終了ページ
- 1596
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acs.orglett.5b00489
- 出版者・発行元
- AMER CHEMICAL SOC
Air- and moisture-stable dibenzo[b,f]gallepins with planar seven-membered rings have been designed and synthesized. From X-ray single-crystal analyses, the effects of the coordination numbers were evaluated at the gallium atom on the planarity of the seven-membered rings with a series of the synthesized complexes. Accordingly, it was shown that the seven-membered ring of dibenzogallepin involving a three-coordinated gallium atom presented the highest planarity compared to other dibenzogallepins with four- or five-coordinated gallium atoms. In addition, from theoretical calculations, it was proposed that the electronic states of the gallium atom in the complexes contributed to the energy levels of LUMOs+1.
- リンク情報
- ID情報
-
- DOI : 10.1021/acs.orglett.5b00489
- ISSN : 1523-7060
- eISSN : 1523-7052
- Web of Science ID : WOS:000351558100062