論文

査読有り
2014年11月

Doping Incompatible Elements into Calcite through Amorphous Calcium Carbonate

CRYSTAL GROWTH & DESIGN
  • Satoshi Matsunuma
  • ,
  • Hiroyuki Kagi
  • ,
  • Kazuki Komatsu
  • ,
  • Koji Maruyama
  • ,
  • Toru Yoshino

14
11
開始ページ
5344
終了ページ
5348
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/cg500953h
出版者・発行元
AMER CHEMICAL SOC

Doping large amounts of a incompatible element into calcite, a polymorph of CaCO3, was achieved by pressurizing amorphous calcium carbonate (ACC) containing a dopant. Strontium-doped ACC samples were prepared from supersaturated solutions. ACC was transformed to calcite at 0.8 GPa and 25 degrees C. The lattice volume of calcite obtained by pressurizing ACC increased monotonically up to 372.5 angstrom 3 (1.3% increase from a Sr-free sample) with increasing Sr content in ACC up to 0.15 in Sr/(Sr + Ca). For comparison, the lattice volumes of calcite samples precipitated from supersaturated CaCO3 solution containing Sr were obtained, but the lattice volume of calcite precipitated from supersaturated solutions showed no noteworthy increase. Results of this study indicate that pressure-induced crystallization is an efficient pathway to dope incompatible elements into crystals.

リンク情報
DOI
https://doi.org/10.1021/cg500953h
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000344516800003&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/cg500953h
  • ISSN : 1528-7483
  • eISSN : 1528-7505
  • Web of Science ID : WOS:000344516800003

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