論文

査読有り
2018年5月

Controllable Direction of Porphyrin Derivatives in Two Cyclodextrin Cavities

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
  • Banri Horiguchi
  • ,
  • Toshimi Nakaya
  • ,
  • Masafumi Ueda
  • ,
  • Kouta Sugikawa
  • ,
  • Tsutomu Mizuta
  • ,
  • Takeharu Haino
  • ,
  • Naomi Kawata
  • ,
  • Atsushi Ikeda

2018
18
開始ページ
2138
終了ページ
2143
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/ejoc.201800433
出版者・発行元
WILEY-V C H VERLAG GMBH

Porphyrin-trimethyl--cyclodextrin (TMe--CDx) complexes have pseudorotaxane structures in which two meso-phenyl and/or -pyridyl moieties penetrate the upper rim of two TMe--CDx molecules. Porphyrin derivatives with one to three pyridyl moieties at meso positions formed complexes with TMe--CDx in which the penetration of the upper rim of the two TMe--CDxs by the pyridyl moieties was minimized. In contrast, in TMe--CDx complexes formed with porphyrin derivatives bearing two 2-methoxyphenyl moieties and two pyridyl moieties, the pyridyl moieties penetrate the upper rim of the two molecules because steric hindrance prevents penetration by the 2-methoxyphenyl moieties.

リンク情報
DOI
https://doi.org/10.1002/ejoc.201800433
CiNii Articles
http://ci.nii.ac.jp/naid/120006627277
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000432225700015&DestApp=WOS_CPL
URL
http://ir.lib.hiroshima-u.ac.jp/00046212
ID情報
  • DOI : 10.1002/ejoc.201800433
  • ISSN : 1434-193X
  • eISSN : 1099-0690
  • CiNii Articles ID : 120006627277
  • Web of Science ID : WOS:000432225700015

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