論文

査読有り
2018年5月

Reactivity of a (Benzene)Ruthenium(II) Cation on a Di-lacunary -Keggin-Type Silicotungstate and Synthesis of a Mono-(Benzene)Ruthenium(II)-Attached -Keggin-Type Silicotungstate

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
  • Masaya Kikuchi
  • ,
  • Hiromi Ota
  • ,
  • Xavier Lopez
  • ,
  • Toshimi Nakaya
  • ,
  • Nao Tsunoji
  • ,
  • Tsuneji Sano
  • ,
  • Masahiro Sadakane

17
開始ページ
1778
終了ページ
1786
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/ejic.201701311
出版者・発行元
WILEY-V C H VERLAG GMBH

Reaction of a (benzene)Ru2+ complex, [Ru(C6H6)Cl-2](2), with a di-lacunary -Keggin-type silicodecatungstate, K-8[-SiW10O36], at a (C6H6)Ru2+/[-SiW10O36](8-) ratio of 1 produces [-SiW10O36Ru(C6H6)](6-). The cesium salt was characterized using experimental and theoretical methods; one (C6H6)Ru2+ moiety is attached through three bridging oxygen atoms of the non-lacunary site, and the anion is stable in aqueous solution. H-1 NMR spectroscopy and high-resolution electrospray ionization mass spectrometry measurements of the reaction mixture with different (C6H6)Ru2+/[-SiW10O36](8-) ratios indicate that the (C6H6)Ru2+ complex first reacts with the three bridging oxygen atoms to form [-SiW10O36Ru(C6H6)](6-), and then react on the terminal oxygen atoms of the lacunary site to form a [-SiW10O36Ru(C6H6)](6-) complex, which was reported by the Kortz and Nadjo group.

リンク情報
DOI
https://doi.org/10.1002/ejic.201701311
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000431635800001&DestApp=WOS_CPL
ID情報
  • DOI : 10.1002/ejic.201701311
  • ISSN : 1434-1948
  • eISSN : 1099-0682
  • Web of Science ID : WOS:000431635800001

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