2020年
Hydrothermal organic acid leaching of positive electrode material of lithium-ion batteries
Kagaku Kogaku Ronbunshu
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- 巻
- 46
- 号
- 5
- 開始ページ
- 167
- 終了ページ
- 175
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1252/kakoronbunshu.46.167
To construct a recycling process for spent lithium-ion batteries, the hydrothermal leaching by organic acid of lith-ium-ion battery positive electrode materials and spent lithium-ion batteries was examined by treatment with citric acid (0.4‒2.0 mol/dm3) at 80‒200°C for 5‒60 min. Leaching efficiencies of Li, Co and Ni were found to increase with increasing reaction temperature and time. The leaching efficiency of Mn was more than 90% under mild conditions of 110°C for 5 min, but it decreased as the reaction temperature increased, and a white solid precipitated. However, when the temperature was further increased, the leaching efficiency increased again. When the effect of reaction temperature on leaching efficiency was investigated with spent lithium-ion batteries, the positive electrode elements Li, Co, Ni and Mn were all leached. Furthermore, it was suggested that in the leaching of spent lithium-ion batteries, the crystal struc-ture of the positive electrode elements was changed by the pretreatment, which affected the leaching mechanism.
- リンク情報
- ID情報
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- DOI : 10.1252/kakoronbunshu.46.167
- ISSN : 0386-216X
- eISSN : 1349-9203
- SCOPUS ID : 85091111819