Abstract

Electrochemical conversion and storage of unutilized renewable energy will contribute to decarbonization. Here, we create the concept of a liquid electrochemical cell that discharges between the anodic and cathodic sides by reverse reactions of the same redox couple in different solvation states, which are created by differences in the mixture ratios of two solvents called the main solvent (MS) and the transferred solvent (TS). The cell can be charged by a transfer of the TS between the discharged anolyte and catholyte. As an example, we demonstrate a cell utilizing a ferro-/ferricyanide redox couple. Stable discharging and charging via the proposed method is achieved by utilizing water (MS) and acetone (TS). Additionally, dominating factors in the design of a high-performance system are discussed, focusing on the electron acceptability of the MS and the TS. The cell voltages are successfully tuned, and a cell voltage of 0.63 V is achieved by the combination of dimethyl sulfoxide (MS) and water (TS). Moreover, the cell can be customized by various electrochemical reaction systems, which can allow multiple options for the charging processes. This concept provides new approaches for the utilization of diverse energy sources as an input for the charging of electrochemical cells.