Papers

Peer-reviewed
May, 1998

Exchange reaction of adsorbed formate with gaseous formic acid on Ni(110) studied by time-resolved Fourier transform infrared reflection absorption spectroscopy

JOURNAL OF PHYSICAL CHEMISTRY B
  • A Yamakata
    • ,
  • J Kubota
    • ,
  • JN Kondo
    • ,
  • C Hirose
    • ,
  • K Domen
    • ,
  • F Wakabayashi
    • ,
  • K Tamaru
Volume
102
Number
22
First page
4401
Last page
4403
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1021/jp981192b
Publisher
AMER CHEMICAL SOC
The dynamic behavior of adsorbed formate on Ni(110) in the presence of gaseous formic acid was studied by time-resolved infrared reflection absorption spectroscopy. The preadsorbed formate (DCOO(a)) was replaced by the postexposed formic acid (HCOOD) to form HCOO(a) on Ni(110) in the temperature region between 230 and 300 K, where the formate was stable under vacuum and no decomposition of formate was observed. It was confirmed that the preadsorbed DCOO(a) desorbed as DCOOD accompanied by formation of HCOO(a) via the deuterium atom transfer from HCOOD.
Link information
DOI
https://doi.org/10.1021/jp981192b
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000074067600023&DestApp=WOS_CPL
ID information
  • DOI : 10.1021/jp981192b
  • ISSN : 1089-5647
  • Web of Science ID : WOS:000074067600023
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