論文

査読有り
2010年6月

Photofunctionalization of a Pentamethylcyclopentadienyl Ligand with the N-Phenylcarbazolyl Group To Prepare a Highly Luminescent Tb3+ Complex Having a Fast Radiation Rate

ORGANOMETALLICS
  • Takeshi Yatabe
  • ,
  • Hidetaka Nakai
  • ,
  • Koichi Nozaki
  • ,
  • Tomoo Yamamura
  • ,
  • Kiyoshi Isobe

29
11
開始ページ
2390
終了ページ
2393
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/om1003094
出版者・発行元
AMER CHEMICAL SOC

Lanthanide(III)bent-metallocene complexes with a novel photofunctionalized pentamethylcyclopentadienyl ligand having an N-phenylcarbazolyl group (Cp-PhCar = eta(5)-C5Me4CH2-C18H12N), [Ln(Cp-PhCar)(2)I(THF)] (Ln = Tb (1), Gd (2)), were prepared and their molecular structures and luminescence properties were investigated. The f-f emission from the terbium metal center of I was efficiently sensitized by Cp-PhCar (epsilon = 0.88 x 10(4) M-1 cm(-1) at 331 nm, Phi = 0.67 at 330 nm excitation, k(r) = 1.68 x 10(3) s(-1)). Additionally, the solid-state structure of potassium salts of C-5-ring (eta(5)-C5R5, R = Me, H) derivatives was uncommonly characterized in Cp-PhCar.

リンク情報
DOI
https://doi.org/10.1021/om1003094
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000278427400003&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/om1003094
  • ISSN : 0276-7333
  • Web of Science ID : WOS:000278427400003

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