2017年
Charge-discharge property of non-stoichiometric lithium iron silicate
ECS Transactions
- ,
- ,
- ,
- 巻
- 80
- 号
- 10
- 開始ページ
- 111
- 終了ページ
- 116
- 記述言語
- 英語
- 掲載種別
- 研究論文(国際会議プロシーディングス)
- DOI
- 10.1149/08010.0111ecst
- 出版者・発行元
- Electrochemical Society Inc.
Lithium iron silicate, Li2FeSiO4 exhibits a high theoretical capacity
however, the reversible charge-discharge reaction is proceeded actually only between the divalent and the trivalent of iron, and the excess lithium ion is not involved. In this study, we attempted to maximize the amount of iron redox couple by synthesizing non-stoichiometric compound compounds. In the highly non-stoichiometric composition, the charge-discharge capacity decreased due to the impurity phase was observed, but in the case of a small amount of lithium deficient composition the capacity increase and the improvement of rate capability were observed.
however, the reversible charge-discharge reaction is proceeded actually only between the divalent and the trivalent of iron, and the excess lithium ion is not involved. In this study, we attempted to maximize the amount of iron redox couple by synthesizing non-stoichiometric compound compounds. In the highly non-stoichiometric composition, the charge-discharge capacity decreased due to the impurity phase was observed, but in the case of a small amount of lithium deficient composition the capacity increase and the improvement of rate capability were observed.
- ID情報
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- DOI : 10.1149/08010.0111ecst
- ISSN : 1938-5862
- ISSN : 1938-6737
- SCOPUS ID : 85046135587