2004年2月5日
Hysteretic behavior on the heat of protonation of diethylenetriamine in aqueous solution
Chemistry Letters
- ,
- ,
- ,
- 巻
- 33
- 号
- 2
- 開始ページ
- 186
- 終了ページ
- 187
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/cl.2004.186
Hysteretic behavior was found on the heat of protonation of diethylenetriamine (dien) in aqueous solution at 298 K. We propose the presence of two conformers for Hdien+, which have significantly different proton affinities. Mutual transformation between the conformers may be practically forbidden, but is strongly accelerated upon their protonation to form H2dien2+.
- リンク情報
- ID情報
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- DOI : 10.1246/cl.2004.186
- ISSN : 0366-7022
- SCOPUS ID : 1942454875