論文

査読有り
2006年3月

Cryogenic NMR spectroscopy of endohedral hydrogen-fullerene complexes

JOURNAL OF CHEMICAL PHYSICS
  • M Carravetta
  • ,
  • OG Johannessen
  • ,
  • MH Levitt
  • ,
  • Heinmaa, I
  • ,
  • R Stern
  • ,
  • A Samoson
  • ,
  • AJ Horsewill
  • ,
  • Y Murata
  • ,
  • K Komatsu

124
10
開始ページ
104507
終了ページ
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1063/1.2174012
出版者・発行元
AMER INST PHYSICS

We have observed H-1 NMR spectra of hydrogen molecules trapped inside modified fullerene cages under cryogenic conditions. Experiments on static samples were performed at sample temperatures down to 4.3 K, while magic-angle-spinning (MAS) experiments were performed at temperatures down to 20 K at spinning frequencies of 15 kHz. Both types of NMR spectra show a large increase in the intramolecular H-1-H-1 dipolar coupling at temperatures below 50 K, revealing thermal selection of a small number of spatial rotational states. The static and MAS spectra were compared to estimate the degree of sample heating in high-speed cryogenic MAS-NMR experiments. The cryogenic MAS-NMR data show that the site resolution of magic-angle-spinning NMR may be combined with the high signal strength of cryogenic operation and that cryogenic phenomena may be studied with chemical site selectivity.

リンク情報
DOI
https://doi.org/10.1063/1.2174012
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000235988400029&DestApp=WOS_CPL
ID情報
  • DOI : 10.1063/1.2174012
  • ISSN : 0021-9606
  • eISSN : 1089-7690
  • Web of Science ID : WOS:000235988400029

エクスポート
BibTeX RIS