2010年5月
Magnetic Interaction of Solution-State Paramagnets with Encapsulated H2O and H-2
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
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- 巻
- 1
- 号
- 9
- 開始ページ
- 1420
- 終了ページ
- 1422
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/jz100336x
- 出版者・発行元
- AMER CHEMICAL SOC
The bimolecular contribution, R-1(M-1 s(-1)), to the T-1 of isolated H-2 and H2O protons, as well as free H2O in organic solution, by paramagnetic metal complexes was determined. Isolation was achieved by encapsulation in a fullerene. H-2 was trapped in pristine C-60 or in C-60 with a 13-atom opening, and H2O in an open-C-60 with a 19-atom opening. The R-1 values in the presence of the various M(acac)(x) complexes [M = Fe(III), Cr(III), Cu(II), Co(III)] scale with mu(2)(eff) of the metal complex. The R-1 values were significantly smaller for the trapped species than the free H2O. Surprisingly, R-1 was nearly identical for the all three endohedral proton pairs, even in different solvents. This suggests that the magnetic isolation effects of the carbon cage are not significantly affected by the solvent, the completeness of the carbon cage, or separation of the hydrogens by an oxygen atom.
- リンク情報
- ID情報
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- DOI : 10.1021/jz100336x
- ISSN : 1948-7185
- Web of Science ID : WOS:000277443200025