論文

査読有り 責任著者
2017年5月

Oxygen-Bridged Diphenylnaphthylamine as a Scaffold for Full-Color Circularly Polarized Luminescent Materials

JOURNAL OF ORGANIC CHEMISTRY
  • Hidetaka Nishimura
  • ,
  • Kazuo Tanaka
  • ,
  • Yasuhiro Morisaki
  • ,
  • Yoshiki Chujo
  • ,
  • Atsushi Wakamiya
  • ,
  • Yasujiro Murata

82
10
開始ページ
5242
終了ページ
5249
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/acs.joc.7b00511
出版者・発行元
AMER CHEMICAL SOC

An oxygen-bridged diphenylnaphthylamine with a helical shape was designed and synthesized as a key scaffold for circularly polarized luminescent (CPL) materials. The introduction of electron-withdrawing groups, such as formyl and 2,2-dicyanovinyl substituents at the naphthyl moiety in this skeleton effectively decreases the LUMO level and thus allows a tuning of the band gap. The prepared model compounds exhibit intense CPL signals with a dissymmetry factor (g value) of 10(-3) both in CH2Cl2 solutions and in the solid states. The emission colors of these derivatives are influenced both by the substituents as well as by solvent effects, covering the whole visible region from blue to deep red.

リンク情報
DOI
https://doi.org/10.1021/acs.joc.7b00511
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000402023200024&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/acs.joc.7b00511
  • ISSN : 0022-3263
  • Web of Science ID : WOS:000402023200024

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