We report a photoelectron imaging study of cryogenically p os cooled C59N- and (C59N)(2)(2-) anions produced from electrospray ionization. High-resolution photoelectron spectra are obtained for C59N- for the first time, allowing seven vibrational frequencies of the C59N azafullerene to be measured. The electron affinity of C59N is determined accurately to be 3.0150 +/- 0.0007 eV. The observed vibrational features are understood on the basis of calculated frequencies and compared with those of C-60 and C59HN. The photoelectron image of (C59N)(2)(2-), which has the same mass/charge ratio as C59N-, is also observed, allowing the second electron affinity of the (C59N)(2) azafullerene dimer to be measured as 1.20 +/- 0.05 eV. The intramolecular Coulomb repulsion of the (C59N)(2)(2-) dianion is estimated to be 1.96 eV and is investigated theoretically using the electron density difference between (C59N)(2)(2-) and (C59N)(2).