論文

2013年

Addition and in situ halo-cyclization of omega-alkenyl Grignard reagents with aldehydes, ketones, carbon dioxide, and azodicarboxylate

NEW JOURNAL OF CHEMISTRY
  • Yasutomo Yamamoto
  • ,
  • Misa Shimizu
  • ,
  • Ai Ohara
  • ,
  • Akari Miyawaki
  • ,
  • Kiyoshi Tomioka

37
12
開始ページ
3873
終了ページ
3876
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1039/c3nj00765k
出版者・発行元
ROYAL SOC CHEMISTRY

An addition reaction of omega-alkenylmagnesium bromide with aldehydes and consecutive oxidative cyclization with iodobenzene diacetate afforded brominated tetrahydrofuran in one pot. The reaction was also applicable to a one-pot synthesis of 2,5,5-trisubstituted tetrahydrofuran, lactone, and pyrazolidine using a ketone, carbon dioxide, and azodicarboxylate, respectively, as electrophiles. One-pot iodo- and chloro-cyclizations were also possible with alkenylmagnesium iodide and chloride.

リンク情報
DOI
https://doi.org/10.1039/c3nj00765k
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000326984000011&DestApp=WOS_CPL
ID情報
  • DOI : 10.1039/c3nj00765k
  • ISSN : 1144-0546
  • eISSN : 1369-9261
  • Web of Science ID : WOS:000326984000011

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