2004年12月
Ni(2+) uptake by amorphous and crystalline Ca(2)Al(2)SiO(7) synthesized by solid-state reaction of kaolinite
SEPARATION AND PURIFICATION TECHNOLOGY
- ,
- ,
- ,
- 巻
- 40
- 号
- 2
- 開始ページ
- 209
- 終了ページ
- 215
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.seppur.2004.02.010
- 出版者・発行元
- ELSEVIER SCIENCE BV
The uptake of Ni(2+) by amorphous and crystalline gehlenite (Ca(2)Al(2)SiO(7)) was investigated. The Ca(2)Al(2)SiO(7) samples were prepared by solid-state reaction of mixtures of kaolinite, calcite, and aluminum hydroxide mechanochemically treated the mixture for 0-24h and fired at 600-900degreesC for 24 h. The mechanochemically treated samples crystallized to form gehlenite at greater than or equal to850degreesC, below which temperature they were amorphous. Ni(2+) uptake experiments were performed by a batch method at 25 degreesC using a solid/solution ratio of 0.002 g ml(-1) and a Ni(2+) concentration of 10(-4); to 5 x 10(-2) M. The uptake capability increased with increasing pH > 6 and decreasing initial Ni(2+) concentration. The amorphous sample showed a higher Ni(2+) uptake than the crystalline sample, and its uptake was also higher than values reported in the literature for amorphous CaAl(2)Si(2)O(8), zeolites, gylorite, and activated carbon. (C) 2004 Elsevier B.V. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.seppur.2004.02.010
- ISSN : 1383-5866
- Web of Science ID : WOS:000224277000012