2006年12月
Synthesis of a phosphorus-containing hybrid porphyrin
ORGANIC LETTERS
- ,
- ,
- ,
- ,
- 巻
- 8
- 号
- 25
- 開始ページ
- 5713
- 終了ページ
- 5716
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ol622763
- 出版者・発行元
- AMER CHEMICAL SOC
A phosphorus-containing hybrid porphyrin was successfully prepared via the BF3-promoted dehydrative condensation between sigma(4)-phosphatripyrrane and 2,5-bis[hydroxy(phenyl)methyl]thiophene. The NMR and UV-vis absorption spectra, electrochemical measurements, and DFT calculations revealed that the sigma(3)-P,N-2,S-hybrid porphyrin exhibits high aromaticity as an 18 pi-electron system in terms of both geometric and magnetic criteria.
- リンク情報
- ID情報
-
- DOI : 10.1021/ol622763
- ISSN : 1523-7060
- eISSN : 1523-7052
- Web of Science ID : WOS:000242405900009