Papers

Peer-reviewed
Aug, 2013

Low-temperature softening due to vacancy orbital with Λ8 quartet ground state in boron-doped floating zone silicon

Journal of the Physical Society of Japan
  • Shotaro Baba
  • ,
  • Mitsuhiro Akatsu
  • ,
  • Keisuke Mitsumoto
  • ,
  • Satoru Komatsu
  • ,
  • Kunihiko Horie
  • ,
  • Yuichi Nemoto
  • ,
  • Hiroshi Yamada-Kaneta
  • ,
  • Terutaka Goto

Volume
82
Number
8
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.7566/JPSJ.82.084604

We have carried out low-temperature ultrasonic measurements using shear-mode ultrasound to clarify the quantum state of a vacancy orbital in boron-doped silicon grown by the floating zone (FZ) method. The elastic constants (C11-C12)=2 and C44 of the transverse mode exhibit considerable softening below 2 and 5K down to the base temperature of 30 mK, respectively. The elastic constant C44 measured by the three ultrasonic modes (kx
uy), (kz
ux), and (kx
uz) shows the different magnetic field dependences among the configurations under applied magnetic fields along the z-axis. The elastic softening and the magnetic field dependence of the elastic constants are accounted for by the quadrupole susceptibility based on the energy level scheme of the vacancy orbital with a λ8 quartet ground state and λ7 doublet excited state located at an energy of 1K. The difference in C44 between the two ultrasonic modes (kz
ux) and (kx
uz) at fields along the z-axis indicates that the λ8 quartet ground state is slightly split by local strain in the silicon sample. The quantum state of the vacancy orbital is expected to be sensitive to strain because of the extremely large quadrupole-strain coupling energy of gλ ≈ 105 K due to the extensively spreading orbital radius of r ≈ 1 nm. The differences in variation of the low-temperature softening and magnetic field dependence among eight samples cut out from different locations of the present boron-doped FZ silicon ingot evidence the inhomogeneous distribution of the vacancy concentration. © 2013 The Physical Society of Japan.

Link information
DOI
https://doi.org/10.7566/JPSJ.82.084604
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000322374300028&DestApp=WOS_CPL
ID information
  • DOI : 10.7566/JPSJ.82.084604
  • ISSN : 0031-9015
  • ISSN : 1347-4073
  • SCOPUS ID : 84880856546
  • Web of Science ID : WOS:000322374300028

Export
BibTeX RIS