Papers

Peer-reviewed
Jan, 2008

Guest Ion Motion in Cage Structure Crystals Investigated by Raman Scattering

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN
  • Masayuki Udagawa
  • Takumi Hasegawa
  • Yuichi Takasu
  • Norio Ogita
  • Koichiro Suekuni
  • Marcos A. Avila
  • Toshiro Takabatake
  • Yoshikazu Ishikawa
  • Naoya Takeda
  • Yuichi Nemoto
  • Terutaka Goto
  • Hitoshi Sugawara
  • Daisuke Kikuchi
  • Hideyuki Sato
  • Chihiro Sekine
  • Ichimin Shirotani
  • Jun-Ichi Yamaura
  • Yohei Nagao
  • Zenji Hiroi
  • Display all

Volume
77
Number
First page
142
Last page
147
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1143/JPSJS.77SA.142
Publisher
PHYSICAL SOC JAPAN

Last five years we have mainly investigated phonons in the following cage compounds by Raman scattering: RT4X12, A(8)Ga(16)Ge(30), La3Pd20Ge6, RB6, KOs2O6. From this systematic investigation we have clarified the following dynamical properties of the guest ion trapped in the large cages. The vibration of the guest ion is highly anharmonic due to weak atomic interaction between the guest ion and cage atom. This anharmonicity universally decreases the vibration energy of the guest ion with decreasing temperature. The existence of carriers decreases the interaction between the guest atoms and changes the dispersion curve of the guest ion mode to flat, which is the experimental evidence of the weak interaction between the guest atoms. For thermoelectricity, it is found in A(8)Ga(16)Ge(30) that the off-center rattling decreases lattice thermal conductivity.

Link information
DOI
https://doi.org/10.1143/JPSJS.77SA.142
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000209384500024&DestApp=WOS_CPL
ID information
  • DOI : 10.1143/JPSJS.77SA.142
  • ISSN : 0031-9015
  • Web of Science ID : WOS:000209384500024

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