1996年
Hydrodesulfurization of benzothiophene catalyzed by molybdenum sulfide cluster encapsulated into zeolites
11TH INTERNATIONAL CONGRESS ON CATALYSIS - 40TH ANNIVERSARY, PTS A AND B
- ,
- ,
- ,
- ,
- ,
- 巻
- 101
- 号
- 開始ページ
- 107
- 終了ページ
- 116
- 記述言語
- 英語
- 掲載種別
- 出版者・発行元
- ELSEVIER SCIENCE PUBL B V
A cationic molybdenum sulfide cluster [Mo3S4(H2O)(9)](4+) with incomplete cubane-type structure and a cationic nickel-molybdenum mixed sulfide cluster [Mo3NiS4Cl(H2O)(9)](3+) With complete cubane-type structure were introduced into zeolites NaY, HUSY and KL by ion exchange. Stoichometry of the ion exchange was well established by elemental analyses. The UV-visible spectra and EXAFS analysis data exhibited that the structure of the molybdenum cluster remained virtually intact after ion exchange. MoNi/NaY catalyst prepared using the molybdenum-nickel sulfide cluster was found to be active and selective for benzothiophene hydrodesulfurization.
- リンク情報
- ID情報
-
- Web of Science ID : WOS:A1996BG17S00011