2003年
Mono(sulfido)-bridged mixed-valence nitrosyl complex: protonation and oxidative addition of iodine across the Ir(II)-Ir(0) bond
CHEMICAL COMMUNICATIONS
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- 巻
- 2003
- 号
- 4
- 開始ページ
- 510
- 終了ページ
- 511
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- 出版者・発行元
- ROYAL SOC CHEMISTRY
Treatment of [Cp*IrH(SH)(PMe3)] (CP* = eta(5)-C5Me5) with [IrCl2(NO)(PPh3)(2)] in the presence of triethylamine yielded the sulfido-bridged (IrIro)-Ir-II complex [Cp*Ir(PMe3)(mu-S)Ir(NO)(PPh3)], which further reacted with I-2 and triflic acid to give the diiodo complex [Cp*Ir(PMe3)(mu-I)(mu-S)IrI(NO)(PPh3)] and the hydrido complex [Cp*Ir(PMe3)(mu-H)(mu-S)Ir(NO)(PPh3)][OSO2CF3], respectively.
- リンク情報
- ID情報
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- ISSN : 1359-7345
- Web of Science ID : WOS:000181302800027