2018年7月5日
Selective Hydrogenation of Nitriles to Secondary Imines over Rh-PVP Catalyst under Mild Conditions
Chemistry Letters
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- ,
- ,
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- 巻
- 47
- 号
- 7
- 開始ページ
- 938
- 終了ページ
- 940
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/cl.180349
- 出版者・発行元
- 公益社団法人 日本化学会
<p>Various metal nanoparticle catalysts (Ru, Rh, Pd, Ir, and Pt) were prepared via liquid-phase reduction and their activity was studied for selective hydrogenation of benzonitrile to corresponding secondary imine under mild conditions (3 bar H2 and 30 °C). The Rh catalyst with particle size of 2.7 nm exhibited excellent activity for the hydrogenation of benzonitrile to secondary imine. The catalyst was reused and applied to transform various nitriles to corresponding secondary imines.</p>
- リンク情報
- ID情報
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- DOI : 10.1246/cl.180349
- ISSN : 0366-7022
- eISSN : 1348-0715
- CiNii Articles ID : 130007402753