2021年4月21日
Illuminating Stannylation
Journal of the American Chemical Society
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- 巻
- 143
- 号
- 開始ページ
- 5629
- 終了ページ
- 5635
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/jacs.1c00887
- 出版者・発行元
- American Chemical Society (ACS)
We have developed photoboosted stannylation reactions of terminal alkynes (linear-selective hydrostannylation) and fluoroarenes (defluorostannylation), in which the stannyl anion is photoexcited to an excited triplet (T1) stannyl diradical species. This unprecedented T1-stannyl diradical species shows completely different reactivity and selectivity from those of stannyl anions and stannyl radicals. This methodology is operationally simple, has broad functional group tolerance, and proceeds in high yield without the need for any catalyst.
- ID情報
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- DOI : 10.1021/jacs.1c00887
- ISSN : 0002-7863
- eISSN : 1520-5126