2020年1月
Helical Pore Alignment on Cylindrical Carbon
Small
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- 巻
- 16
- 号
- 2
- 開始ページ
- 1905916
- 終了ページ
- 1905916
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/smll.201905916
- 出版者・発行元
- Wiley
Interest in chiral substances has mainly focused on the substances themselves, but not on the accompanying space, especially regarding the pore alignment. As a method to form both the chiral substance and the accompanying space, cylindrical self-assembly of uniform polystyrene nanoparticles with fructose is carried out in the presence of both carbon and sodium alginate, which is followed by heat treatment in an inert atmosphere. The carbonization generates fructose-derived honeycomb-like carbon walls with helically aligned nanopores left after the polystyrene decomposition. The diffuse reflectance circular dichroism measurements give peaks with opposite signs for the d- and l-fructose-derived cylindrical carbons. Circularly polarized light sensitivity in transient photoconductivity is confirmed apparently in the carbon-based helical structures. This sensitivity as well as straightforward formation of composites with another component to give helicity shows potential applications of the helically aligned pores.
- リンク情報
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- DOI
- https://doi.org/10.1002/smll.201905916
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000500720500001&DestApp=WOS_CPL
- URL
- https://onlinelibrary.wiley.com/doi/pdf/10.1002/smll.201905916
- URL
- https://onlinelibrary.wiley.com/doi/full-xml/10.1002/smll.201905916
- URL
- https://onlinelibrary.wiley.com/doi/am-pdf/10.1002%2Fsmll.201905916
- ID情報
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- DOI : 10.1002/smll.201905916
- ISSN : 1613-6810
- eISSN : 1613-6829
- Web of Science ID : WOS:000500720500001