2018年1月
Synthesis of partially and fully fused polyaromatics by annulative chlorophenylene dimerization
SCIENCE
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- 巻
- 359
- 号
- 6374
- 開始ページ
- 435
- 終了ページ
- +
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1126/science.aap9801
- 出版者・発行元
- AMER ASSOC ADVANCEMENT SCIENCE
Since the discovery by Ullmann and Bielecki in 1901, reductive dimerization (or homocoupling) of aryl halides has been extensively exploited for the generation of a range of biaryl-based functional molecules. In contrast to the single-point connection in these products, edge-sharing fused aromatic systems have not generally been accessible from simple aryl halides via annulation cascades. Here we report a single-step synthesis of fused aromatics with a triphenylene core by the palladium-catalyzed annulative dimerization of structurally and functionally diverse chlorophenylenes through double carbon-hydrogen bond activation. The partially fused polyaromatics can be transformed into fully fused, small graphene nanoribbons, which are otherwise difficult to synthesize. This simple, yet powerful, method allows access to functional p-systems of interest in optoelectronics research.
- リンク情報
- ID情報
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- DOI : 10.1126/science.aap9801
- ISSN : 0036-8075
- eISSN : 1095-9203
- ORCIDのPut Code : 55708161
- Web of Science ID : WOS:000423283200041