論文

2019年5月

Dense yet highly ion permeable graphene electrodes obtained by capillary-drying of a holey graphene oxide assembly

JOURNAL OF MATERIALS CHEMISTRY A
  • Xiangrong Chen
  • ,
  • Junwei Han
  • ,
  • Xiaohui Lv
  • ,
  • Wei Lv
  • ,
  • Zhengze Pan
  • ,
  • Chong Luo
  • ,
  • Siwei Zhang
  • ,
  • Qiaowei Lin
  • ,
  • Feiyu Kang
  • ,
  • Quan-Hong Yang

7
20
開始ページ
12691
終了ページ
12697
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1039/c9ta03698a
出版者・発行元
ROYAL SOC CHEMISTRY

The density and ion channel abundancy of an electrode material must be elaborately balanced to achieve a high volumetric energy density for any energy storage devices. As a typical example, graphene shows great potential in different energy storage devices but its low density and ion diffusion barrier effect limit its practical uses. In the present work, H2O2 etching was introduced into the hydrothermal assembly of graphene oxide (GO) to decrease the lateral size of GO and create in-plane holes, and after a capillary drying process, a high-density holey graphene monolith (HHGM) with numerous and interconnected ion transporting channels was obtained. The smaller sheet size leads to a more densified assembly while in-plane holes are beneficial to ion transportation in the HHGM, which well balance the high density and fast ion diffusion in the electrode. As a result, the HHGM shows an impressive rate performance, coupled with a high volumetric capacitance.

リンク情報
DOI
https://doi.org/10.1039/c9ta03698a
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000472219400030&DestApp=WOS_CPL
ID情報
  • DOI : 10.1039/c9ta03698a
  • ISSN : 2050-7488
  • eISSN : 2050-7496
  • Web of Science ID : WOS:000472219400030

エクスポート
BibTeX RIS