論文

査読有り
2010年1月

Crystallization of Poly(butylene terephthalate) from the Glass

MACROMOLECULES
  • Takashi Konishi
  • ,
  • Yoshihisa Miyamoto

43
1
開始ページ
375
終了ページ
383
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/ma9017058
出版者・発行元
AMER CHEMICAL SOC

Crystallization from the glass of poly(butylene terephthalate) (PBT) has been investigated by small-angle X-ray scattering and differential scanning calorimetry. When PBT crystallizes from the glassy state, the nodule crystalline structures ill nanometer scale forms and the micrometer order objects, i.e., spherulites, are not observed. The nodule size grows and Saturates at a given annealing temperature and increases with increasing annealing temperature. Two temperatures are obtained by the linear extrapolation of the temperature dependence of the reciprocal nodule Size to naught. The equilibrium melting temperatures by the Gibbs-Thomson plot, i.e., the melting temperature versus reciprocal nodule size, ire also the same temperatures. The lower extrapolated temperature corresponds to the equilibrium melting temperature of the alpha-form of PBT. The higher extrapolated temperature is discussed oil the basis of the Strobl crystallization model and can be regarded as the equilibrium mesophase-crystal transition temperature.

リンク情報
DOI
https://doi.org/10.1021/ma9017058
J-GLOBAL
https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201002273050447838
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000273268700050&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/ma9017058
  • ISSN : 0024-9297
  • J-Global ID : 201002273050447838
  • Web of Science ID : WOS:000273268700050

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