2014年3月24日
Diprotonated [28]hexaphyrins(1.1.1.1.1.1): Triangular antiaromatic macrocycles
Angewandte Chemie - International Edition
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- 巻
- 53
- 号
- 13
- 開始ページ
- 3427
- 終了ページ
- 3431
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/anie.201400301
- 出版者・発行元
- Wiley-VCH Verlag
Protonation of meso-aryl [28]hexaphyrins(1.1.1.1.1.1) triggered conformational changes. Whereas protonation with trifluoroacetic acid led to the formation of monoprotonated Möbius aromatic species, protonation with methanesulfonic acid led to the formation of diprotonated triangular antiaromatic species. A peripherally hexaphenylated [28]hexaphyrin was rationally designed and prepared to undergo diprotonation to favorably afford a triangular-shaped antiaromatic species. Protonation of [28]hexaphyrins(1.1.1.1. 1.1) triggers conformational changes. Whereas protonation with trifluoroacetic acid leads to the formation of monoprotonated Möbius aromatic species, protonation with methanesulfonic acid leads to the formation of diprotonated triangular antiaromatic species. A peripherally hexaphenylated [28]hexaphyrin was rationally designed to undergo diprotonation to afford a triangular-shaped antiaromatic species. © 2014 WILEY-VCH Verlag GmbH &
Co. KGaA, Weinheim.
Co. KGaA, Weinheim.
- ID情報
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- DOI : 10.1002/anie.201400301
- ISSN : 1521-3773
- ISSN : 1433-7851
- SCOPUS ID : 84896489194