論文

査読有り
2015年1月

Reversible Solid-to-Liquid Phase Transition of Coordination Polymer Crystals

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • Daiki Umeyama
  • ,
  • Satoshi Horike
  • ,
  • Munehiro Inukai
  • ,
  • Tomoya Itakura
  • ,
  • Susumu Kitagawa

137
2
開始ページ
864
終了ページ
870
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/ja511019u
出版者・発行元
AMER CHEMICAL SOC

The solid-to-liquid phase transition, a fundamental process commonly observed for various types of substances with significant potential for application, has been given little attention in the field of coordination polymers (CPs) despite the rich functionality of these compounds. In this article, we report the reversible solid-to-liquid phase transition of crystalline CPs. These CPs are composed of zinc ions, phosphate, and azoles, and a well-balanced composition, ionicity, and bond strength afford melting CPs. We examined the structure of one such melting framework in the liquid and glass states and found that the coordination bonds are not fully preserved in the liquid state but are re-formed in the glass state. As a demonstration, we fabricated, via phase transition, a thin film with an aligned crystal orientation and a monolith crystal of the CP.

Web of Science ® 被引用回数 : 84

リンク情報
DOI
https://doi.org/10.1021/ja511019u
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000348483400052&DestApp=WOS_CPL
URL
http://www.scopus.com/inward/record.url?eid=2-s2.0-84921533844&partnerID=MN8TOARS
URL
http://orcid.org/0000-0003-4830-6888

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