論文

査読有り
2017年12月

Direct observation of new particle formation during ozonolysis of isoprene and ethene competing against the growth of preexisting particles

ATMOSPHERIC ENVIRONMENT
  • Satoshi Inomata
  • ,
  • Kei Sato
  • ,
  • Yosuke Sakamoto
  • ,
  • Jun Hirokawa

170
開始ページ
149
終了ページ
155
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.atmosenv.2017.09.053
出版者・発行元
PERGAMON-ELSEVIER SCIENCE LTD

Secondary organic aerosol formation during the ozonolysis of isoprene and ethene in the presence of ammonium nitrate seed particles (surface area concentrations = (0.8-3) x 10(7) nm(2) cm(-3)) was investigated using a 1 nm scanning mobility particle sizer. Based on the size distribution of formed particles, particles with a diameter smaller than the minimum diameter of the seed particles (less than similar to 6 nm) formed under dry conditions, but the formation of such particles was substantially suppressed during isoprene ozonolysis and was not observed during ethane ozonolysis under humid conditions. We propose that oligomeric hydroperoxides generated by stabilized Criegee intermediates (sCIs), including C-1-sCI (CH2OO), contribute to new particle formation while competing to be taken up onto preexisting particles. The OH reaction products of isoprene and ethene seem to not contribute to new particle formation; however, they are taken up onto preexisting particles and contribute to particle growth. (C) 2017 Elsevier Ltd. All rights reserved.

リンク情報
DOI
https://doi.org/10.1016/j.atmosenv.2017.09.053
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000415772800014&DestApp=WOS_CPL
URL
http://www.scopus.com/inward/record.url?eid=2-s2.0-85030309004&partnerID=MN8TOARS
URL
http://orcid.org/0000-0002-9863-4241
ID情報
  • DOI : 10.1016/j.atmosenv.2017.09.053
  • ISSN : 1352-2310
  • eISSN : 1873-2844
  • ORCIDのPut Code : 46052591
  • SCOPUS ID : 85030309004
  • Web of Science ID : WOS:000415772800014

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