2017年12月
Direct observation of new particle formation during ozonolysis of isoprene and ethene competing against the growth of preexisting particles
ATMOSPHERIC ENVIRONMENT
- ,
- ,
- ,
- 巻
- 170
- 号
- 開始ページ
- 149
- 終了ページ
- 155
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.atmosenv.2017.09.053
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
Secondary organic aerosol formation during the ozonolysis of isoprene and ethene in the presence of ammonium nitrate seed particles (surface area concentrations = (0.8-3) x 10(7) nm(2) cm(-3)) was investigated using a 1 nm scanning mobility particle sizer. Based on the size distribution of formed particles, particles with a diameter smaller than the minimum diameter of the seed particles (less than similar to 6 nm) formed under dry conditions, but the formation of such particles was substantially suppressed during isoprene ozonolysis and was not observed during ethane ozonolysis under humid conditions. We propose that oligomeric hydroperoxides generated by stabilized Criegee intermediates (sCIs), including C-1-sCI (CH2OO), contribute to new particle formation while competing to be taken up onto preexisting particles. The OH reaction products of isoprene and ethene seem to not contribute to new particle formation; however, they are taken up onto preexisting particles and contribute to particle growth. (C) 2017 Elsevier Ltd. All rights reserved.
- リンク情報
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- DOI
- https://doi.org/10.1016/j.atmosenv.2017.09.053
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000415772800014&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-85030309004&partnerID=MN8TOARS
- URL
- http://orcid.org/0000-0002-9863-4241
- ID情報
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- DOI : 10.1016/j.atmosenv.2017.09.053
- ISSN : 1352-2310
- eISSN : 1873-2844
- ORCIDのPut Code : 46052591
- SCOPUS ID : 85030309004
- Web of Science ID : WOS:000415772800014