Papers

Peer-reviewed
2011

Isolation and structural characterization of magic silver clusters protected by 4-(tert-butyl)benzyl mercaptan

CHEMICAL COMMUNICATIONS
  • Yuichi Negishi
  • ,
  • Rio Arai
  • ,
  • Yoshiki Niihori
  • ,
  • Tatsuya Tsukuda

Volume
47
Number
20
First page
5693
Last page
5695
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1039/c0cc05587e
Publisher
ROYAL SOC CHEMISTRY

Small silver clusters (average diameter of 1.2 nm) protected by 4-(tert-butyl)benzyl mercaptan (BBSH) were converted to stable, monodisperse clusters (2.1 nm) by a ripening process with excess amount of BBSH. Multiple characterizations of the isolated magic clusters revealed an approximate chemical composition of Ag(similar to 280)(SBB)(similar to 120).

Link information
DOI
https://doi.org/10.1039/c0cc05587e
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000290168100005&DestApp=WOS_CPL
URL
http://pubs.rsc.org/en/Content/ArticleLanding/2011/CC/c0cc05587e#!divAbstract
ID information
  • DOI : 10.1039/c0cc05587e
  • ISSN : 1359-7345
  • Web of Science ID : WOS:000290168100005

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