2012年2月
Comb-shaped graft copolymers with cellulose side-chains prepared via click chemistry
CARBOHYDRATE POLYMERS
- ,
- ,
- ,
- 巻
- 87
- 号
- 3
- 開始ページ
- 2237
- 終了ページ
- 2245
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.carbpol.2011.10.055
- 出版者・発行元
- ELSEVIER SCI LTD
Comb-shaped copolymers with cellobiose acetate or cellulose triacetate (CIA) side-chains. PPMA-g-(CTA2-C15) and PPMA-g-(CTA13-C15), were prepared by grafting N-(15-azidopentadecanoyl)-2,3,6-tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl)-beta-D-glucopyranosylamine (CTA2-C15-N-3) and N-(15-azidopentadecanoyl)-tri-O-acetyl-beta-cellulosylamine (CTA13-C15-N-3, number average degree of polymerization (DPn) = 13) onto poly(2-propyn-1-yl methacrylate) (PPMA, weight average degree of polymerization (DPw, X + Y = 5.59 x 10(2))) via "click chemistry". The copolymers were characterized by H-1, C-13 and two-dimensional NMR and size exclusion chromatography-multi-angle laser light scattering (SEC-MALS) measurements. The numbers of CIA side-chains (X) of PPMA-g-(CTA2-C15) and PPMA-g-(CTA13-C15) were calculated as 4.03 x 10(2) and 2.45 x 10(2), respectively. Copolymers with cellulosic side-chains, PPMA-g-(CELL2-C15) and PPMA-g-(CELL13-C15), were successfully obtained after deacetylation of PPMA-g-(CTA2-C15) and PPMA-g-(CTA13-C15), respectively. X-ray diffraction measurements revealed that PPMA-g-(CELL13-C15) showed crystalline pattern of cellulose II, which is believed to have anti-parallel orientation. (C) 2011 Elsevier Ltd. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.carbpol.2011.10.055
- ISSN : 0144-8617
- Web of Science ID : WOS:000299969700052