2021年9月
Inorganic/Organic Micro-Double-Network Ion Gel-Based Composite Membrane with Enhanced Mechanical Strength and CO2 Permeance
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
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- 巻
- 60
- 号
- 34
- 開始ページ
- 12698
- 終了ページ
- 12708
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acs.iecr.1c02228
- 出版者・発行元
- AMER CHEMICAL SOC
An inorganic/organic micro-double-network (mu-DN) ion gel-based composite membrane with good mechanical properties and high CO2 permeance was developed in this study. The mu-DN ion gel was composed of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C(4)mim][Tf2N]), a cross-linked polymer network, and silica nanoparticle clusters. The mechanical strength of the mu-DN ion gel was optimized to achieve a fracture energy of 636 kJ/m(3). The fabricated composite membrane with an ion gel layer thickness of 4.5 mu m shows a CO2/N-2 permselectivity of 23 and a CO2 permeance of 119 GPU. The gas permeance of the composite membranes was calculated by considering a series of diffusion processes, and the results were in good agreement with the experimental data. The calculation results obtained using the proposed model show high potential of our mu-DN ion gel to achieve much higher CO2 permeance.
- リンク情報
- ID情報
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- DOI : 10.1021/acs.iecr.1c02228
- ISSN : 0888-5885
- Web of Science ID : WOS:000693080800021