2022年4月6日
Novel Tough Ion-Gel-Based CO2 Separation Membrane with Interpenetrating Polymer Network Composed of Semicrystalline and Cross-Linkable Polymers
Industrial & Engineering Chemistry Research
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- 巻
- 61
- 号
- 13
- 開始ページ
- 4648
- 終了ページ
- 4658
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acs.iecr.1c04800
- 出版者・発行元
- American Chemical Society (ACS)
A tough ion gel constructed from an interpenetrating polymer network (IPN) and high ionic liquid (IL) content was developed using a one-pot/one-step method. The IPN structure was composed of the physically cross-linked poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) network and the chemically cross-linked poly(N,N-dimethylacrylamide-co-N-succinimidyl acrylate) (poly(DMAAm-co-NSA)) network, which, respectively, contributed to the high mechanical strength and good IL holding property of the IPN ion gel. The IPN ion gel containing 80 wt % of IL, 10 wt % of PVDF-HFP network, and 10 wt % of poly(DMAAm-co-NSA) network prepared at 50 °C displayed high tensile fracture energy (758 kJ/m3) and a good IL holding property under compression at 1.16 MPa (weight loss of the ion gel: 0.79 wt %). An IPN ion gel membrane with a high IL content of 91.3 wt % was successfully fabricated and showed a high CO2 permeability of 1421 barrer and CO2/N2 permselectivity of 27.
- リンク情報
- ID情報
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- DOI : 10.1021/acs.iecr.1c04800
- ISSN : 0888-5885
- eISSN : 1520-5045
- SCOPUS ID : 85127843805