2017年
Crystal structure of bis(1-ethylpyridinium) dioxonium hexacyanidoferrate(II)
Acta Crystallographica Section E: Crystallographic Communications
- ,
- 巻
- 73
- 号
- 開始ページ
- 219
- 終了ページ
- 222
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1107/S2056989017000810
- 出版者・発行元
- International Union of Crystallography
The title compound, (C7H10N)2(H3O)2[Fe(CN)6] or (Etpy)2(H3O)2[Fe(CN)6] (Etpy+ is 1-ethylpyridinium), crystallizes in the space group Pnnm. The FeII atom of the [Fe(CN)6]4- anion lies on a site with site symmetry..2/m, and has an octahedral coordination sphere defined by six cyanido ligands. Both the Etpy+ and the oxonium cations are located on a mirror plane. In the crystal, electron-donor anions of [Fe(CN)6]4- and electron-acceptor cations of Etpy+ are each stacked parallel to the b axis, resulting in a columnar structure with segregated moieties. The crystal packing is stabilized by a three-dimensional O - H⋯N hydrogen-bonding network between the oxonium ions and the cyanide ligands of [Fe(CN)6]4-.
- ID情報
-
- DOI : 10.1107/S2056989017000810
- ISSN : 2056-9890
- ORCIDのPut Code : 30952691
- SCOPUS ID : 85011568234