We present a systematic method of constructing rational mappings as er odic transformations with nonuniform invariant measures on the unit interval I = [0,1]. As a result, we obtain a two-parameter family of rational mappings that have a special property in that their invariant measures can be explicitly written in terms of algebraic functions of parameters and a dynamical variable. Furthermore, it is shown here that this family is the most generalized class of rational mappings possessing the property of exactly solvable chaos on I, including the Ulam-von Neumann map y = 4x(1-x). Based on the present method, we can produce a series of rational mappings resembling the asymmetric shape of the experimentally obtained first return maps of the Beloussof-Zhabotinski chemical reaction, and we can match some rational functions with other experimentally obtained first return maps in a systematic manner.