2005
Preparation of aluminum oxide-hybridized hydroxyapatite powder by the sol-gel method
Journal of the Ceramic Society of Japan
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- Volume
- 113
- Number
- 1315
- First page
- 241
- Last page
- 244
- Language
- Japanese
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.2109/jcersj.113.241
- Publisher
- Ceramic Society of Japan
Hydroxyapatite powders (HAp
Ca10(PO4) 6(OH)2) hybridized with 0-5 mass % Al2O 3 were prepared from calcium hydroxide and di-aminonium hydrogenphosphate by a wet chemical synthesis. Ethylacetoacetate Aluminum Diisopropoxide (Al(OC3H7)2(C6H 9O3)) was used as a source for aluminum oxide. The obtained powders were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) specific surface area measurement, and magic angle spinning-nuclear magnetic resonance spectroscopy (MAS-NMR). The X-ray diffraction patterns showed no Al2O3-peaks irrespective of Al2O3 content, suggesting that the Al2O 3-hybridized HAp powders were single phase. The Al2O 3-hybridized HAp powder had larger specific surface area. According to MAS-NMR analysis, it was considered that the aluminum element existed as aluminum oxide, it was not substituted for the Ca2+, PO 4 3-, or OH- ions.
Ca10(PO4) 6(OH)2) hybridized with 0-5 mass % Al2O 3 were prepared from calcium hydroxide and di-aminonium hydrogenphosphate by a wet chemical synthesis. Ethylacetoacetate Aluminum Diisopropoxide (Al(OC3H7)2(C6H 9O3)) was used as a source for aluminum oxide. The obtained powders were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) specific surface area measurement, and magic angle spinning-nuclear magnetic resonance spectroscopy (MAS-NMR). The X-ray diffraction patterns showed no Al2O3-peaks irrespective of Al2O3 content, suggesting that the Al2O 3-hybridized HAp powders were single phase. The Al2O 3-hybridized HAp powder had larger specific surface area. According to MAS-NMR analysis, it was considered that the aluminum element existed as aluminum oxide, it was not substituted for the Ca2+, PO 4 3-, or OH- ions.
- Link information
- ID information
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- DOI : 10.2109/jcersj.113.241
- ISSN : 0914-5400
- SCOPUS ID : 17044412671