In the Nelson model particles interact through a scalar massless field. For hydrogen-like atoms there is a nucleus of infinite mass and charge Ze, Z > 0, fixed at the origin and an electron of mass in and charge e. This system forms a bound state with binding energy E-bin= me(4)Z(2)/8pi(2) to leading order in e. We investigate the radiative corrections to the binding energy and prove upper and lower bounds which imply that E-bin = me(4)Z(2)/8pi(2) + c(0)e(6) + O(e(7) ln e) with explicit coefficient c(0) and independent of the ultraviolet cutoff. c(0) can be computed by perturbation theory, which however is only formal since for the Nelson Hamiltonian the smallest eigenvalue sits exactly at the bottom of the continuous spectrum. (C) 2004 Elsevier Inc. All rights reserved.