2014年1月12日
The formation of organogels and helical nanofibers from simple organic salts
Chemistry - A European Journal
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- 巻
- 20
- 号
- 49
- 開始ページ
- 16279
- 終了ページ
- 16285
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/chem.201404043
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Simple organic salts based on aniline-derived cations and D-tartrate anions formed organogels and helical nanofibers. The organic salt (p-fluoroanilinium)(D-tartrate) was found to generate an organogel despite the absence of a hydrophobic alkyl chain, whereas (p-iodoanilinium)(D-tar-trate) formed helical nanofibers in braided ropelike structures through a rolling-up process. The helicity of these nanofibers could be reversed by changing the growth solvent. The driving forces responsible for the formation of the nanofibers were determined to be 1D O-H···O∼ hydrogen-bonding interactions between D-tartrate anions and p stacking of anilinium cations, as well as steric hindrance between the hydrogen-bonded chains.
- リンク情報
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- DOI
- https://doi.org/10.1002/chem.201404043
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/25308219
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000345515700033&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84915747563&origin=inward
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=84915747563&origin=inward
- ID情報
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- DOI : 10.1002/chem.201404043
- ISSN : 0947-6539
- eISSN : 1521-3765
- PubMed ID : 25308219
- SCOPUS ID : 84915747563
- Web of Science ID : WOS:000345515700033