2015
Elemental substitution effects in multiferroic RFe2O4 (R: rare earths)
PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 12, NO 6
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- Volume
- 12
- Number
- 6
- First page
- 841
- Last page
- 844
- Language
- English
- Publishing type
- Research paper (international conference proceedings)
- DOI
- 10.1002/pssc.201400250
- Publisher
- WILEY-V C H VERLAG GMBH
We report the effects of elemental substitutions in multiferroic RFe2O4 (R: Y, Ho-Lu, In). The substitution by nonmagnetic Ga3+ at the Fe site, which has not been reported so far, shows a drastic decrease in the ferrimagnetic transition temperature (TN). This is plausibly owing to the suppression of magnetic interactions between Fe ions, based on our previous results of other substituted systems such as RFeCoO4. Dielectric constants near room temperature were comparable to those of RFe2O4. The suppression of dielectric loss in this system is suitable to application. The R-site substitution was also attempted by the large R3+ ions such as Dy3+. The solubility limit was up to similar to 10% of R ions. TN was raised by 5-10 K for Dy3+ substitution. (C) 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
- Link information
- ID information
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- DOI : 10.1002/pssc.201400250
- ISSN : 1862-6351
- Web of Science ID : WOS:000360198000084