論文

2002年12月

Correlation between hydrophobic hydrophobic attraction and the free energy of hydration

MOLECULAR PHYSICS
  • K Koga
  • ,
  • P Bhimalapuram
  • ,
  • B Widom

100
24
開始ページ
3795
終了ページ
3801
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1080/00268970210162899
出版者・発行元
TAYLOR & FRANCIS LTD

We correlate the strength of the solvent-mediated attraction of a pair of hydrophobic solute molecules with the free energy of hydration of a single such molecule. This is done in the framework of a particular model but the results may be more general. When the model parameters are chosen to represent methane as the solute in water it is found that over the relevant temperature range the strength of the attraction, expressed as a multiple of the thermal energy kT, increases nearly linearly with increasing hydration free energy expressed in the same units. In the middle of the temperature range studied the strength of the attraction is roughly one-third of the hydration free energy.

リンク情報
DOI
https://doi.org/10.1080/00268970210162899
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000180297200004&DestApp=WOS_CPL
ID情報
  • DOI : 10.1080/00268970210162899
  • ISSN : 0026-8976
  • eISSN : 1362-3028
  • Web of Science ID : WOS:000180297200004

エクスポート
BibTeX RIS