2016年12月1日
3,3-Dibromo-2-trifluoromethyl acrylic acid ethyl ester: A versatile platform for the stereoselective preparation of functionalized-α-trifluoromethyl α,β-unsaturated lactones and trifluoromethyl pyrazolinones
Organic Chemistry Frontiers
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- 巻
- 3
- 号
- 12
- 開始ページ
- 1661
- 終了ページ
- 1667
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1039/c6qo00360e
- 出版者・発行元
- Royal Society of Chemistry
We herein describe a method for synthetic routes to multi-functionalized-α-trifluoromethyl α,β-unsaturated lactones and trifluoromethyl pyrazolinones. This involves a tandem stereoselective functionalization of 3,3-dibromo-2-trifluoromethyl acrylic acid ethyl ester and intramolecular cyclization reaction to afford precursors for a Suzuki-Miyaura cross-coupling reaction with arylboronic acids.
- リンク情報
- ID情報
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- DOI : 10.1039/c6qo00360e
- ISSN : 2052-4129
- ISSN : 2052-4110
- ORCIDのPut Code : 29233832
- SCOPUS ID : 84996560113
- Web of Science ID : WOS:000388675600009